_Here we go again right?

So, how many eco websites have you seen touting the supreme green cleaning abilities of WHITE vinegar? (Not to be confused with white WINE vinegar)

For windows, for fabric softening, for tiles, for toilets, for sinks... for just about everything & anything, right? Its great stuff - I've used it... up till now.
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White Vinegar - Is it REALLY the green?
_Well, my research obsessed Bloodhound’s nose sniffed around a bit on this one. I wanted to know how white vinegar was made so I could stop buying it in plastic containers & make my own. I was trying to do the right thing... honestly... but then...

… I uncovered a whole lot of half truthes about white vinegar and it appears that it is FAR from being a totally "green" product. In fact, seems to be the whole process of creation to use is pretty UN-green from what I can gather... but like I say, there's a lot of half truths or not quite upfront truths around how its actually made. It was really a challenge to find out anything about it!

White vinegar, in some instances (most cheap stuff I've seen) is also known as food grade "acetic acid". Now, acetic acid is the technical / chemical name for a naturally occuring substance which is vinegar however it is also the synthetic version thereof... so you can have synthetic acetic acid made in a large scale lab / manufacturing plant and you can have the naturally occuring version.

Full strength synthetic acetic acid is actually highly corrosive & the full on rubber gloves need to be worn when handling it in a lab. So its pretty full on stuff to be watering down and eating on our fish.

White vinegar that is food grade acetic acid is generally made in a lab - as far as I can find out.

Its does not appear to be the naturally occuring kind as this is generally referred to on the label i.e. "distilled from grain" etc. The cheaper white vinegars don't appear to be made in a distillery or brewery (like white wine vinegar or apple cider vinegar... basically unless it says "distilled" on the label its not a distilled or fermented product and not the naturally occuring kind - make sense?).

Looks to me like the cheaper white vinegars we use for cleaning our homes are made in a petrie dish (synthetically I mean). Not real keen on that idea am I. 

Now, not ALL countries in the world approve the use of synthetically created acetic acid for human consumption - but USA, EU & Australia do. Personally, I am not down with that - at all.

The FDA in USA (whom our own FSA copy from unashamedly) says this about white vinegar production:

“Presently, we authorize the manufacture of vinegar from ethyl alcohol synthesized from natural gas or petroleum derivatives. It is our opinion that most of the distilled spirits used in the production of vinegar are derived from natural gas and petroleum…

FDA POLICY:
Synthetic ethyl alcohol may be used as a food ingredient or in the manufacturing of vinegar or other chemicals for food use, within limitations imposed by the Federal Food, Drug, and Cosmetic Act, the Alcohol Administration Act, and regulations promulgated under these acts”.

Now, if you hunt around a bit, you’ll probably find that white vinegar is touted as being distilled alcohol with grains in it.

Yes, that IS correct - SOME types of white vinegar are naturally derived, distilled from grain... but NOT ALL white vinegars are created equal!

Unless your WHITE vinegar bottle says or makes reference to on the label “distilled” then it likely NOT gone through the distillation & fermentation process and likely been created synthetically using petroleum derivatives and other interesting things.

It appears the differentiating labelling for the synthetic version vs the natural version is “acetic acid”.

Got that? Labelled "Distilled" = likely to be fermented grains with alcohol like rice vinegar for example.

Labelled "Acetic acid" = likely to be made in a lab or petrochemically derived.

Now that may not be in ALL cases but I can't confirm for you either way with ANYONE (I've contacted all major white vinegar companies in Australia numerous times for assurances but none have been forthcoming) AND the information I have found states that most white vinegar production in the States and Australia is through adding alcohol (ethanol) to whatever substance (ethyl acetate is one of them) but doesn't at all involve DISTILLING the vinegar itself. Confusing hey?

Check the label on the bottle if you're unsure or concerned - your white vinegar bottle may say "distilled" or it may say something like “dilute acetic acid 5%”.

From all the resarch I've done and the FDA policy on the matter, it appears when a product is labelled "acetic acid" (which most of the cheapie white vinegars are) that it is probably the synthetically produced version of vinegar created industrially (see the FDA policy above).

In the food industry, acetic acid is recognised by the code E260 & is used in condiments as an acidity regulator. Acetic acid is approved for food in Australia, New Zeland, the EU and USA - not globally.

So not all countries in the world are as silly enough to be legalising this type of thing... oddly enough.

Picture
The earth doesn't need it - let's mine it!
_In order to produce or make the synthetically derived product called "acetic acid" there are two methods.

The first and most widely used is Methanol Carbonylation. This involves using carbon monoxide & methanol to produce a reaction to create acetic acid.

In order for that chemical chain reaction to occur, a catalyst is needed. Back in the day, the catalyst was rhodium - a bi-product from platinum mining.

Nowadays, the cheaper & supposedly “greener” alternative is iridium... yet another bi-product from platinum mining & is actually one of the rarest minerals in the earth’s crust.

Its considered an impurity in platinum mining so is extracted & tossed into the acetic acid production processes.

The first company to go with large scale industrial production processes for acetic acid was none other than... MONSANTO. The global genetic engineering giant who produces things like Roundup pesticides and genetically modified seeds.

Don't know about you but when I hear Monstanto involved in ANYTHING I run a mile the other way... that's just me though. You can make up your own mind.

The new process for acetic acid production using iridium is the brain child of BP CHEMICALS.

I'm not really a fan of them either, in terms of natural living & green cleaning!

The second (although not widely used as its expensive) way of producing acetic acid is through a process called “acetaldehyde process”. Again, acetaldehyde CAN be a naturally occuring substance BUT rarely do I see or hear of the natural stuff. Its usually the easily created, petro-chemical version because it uses up left over stuff from the industry.

Yes a good way to use up things but no, not entirely natural, green or eco-friendly. That's my beef here...

Whilst apparently this substance occurs naturally, it appears that the acetaldehyde use in this process is produced via oxidation of butane or light naphtha, or by hydration of ethylene. When butane or light naphtha is heated with air in the presence of various metal ions, including those of manganese, cobalt, and chromium, peroxides form, it then decomposes to produce acetic acid.

Oh, and Naphtha? That’s a very broad term covering the lightest liquid hydrocarbons found in... petroleum.

As I say, its VERY hard to determine from the crappy labelling what type of vinegar you have in your hands - the synthetic version or the "natural" version. Until I know for sure, I won't be using white vinegar at all to clean my home.

Synthetically. Derived. Chemicals. Isn't. Eco. Well, not to me anyway. Again, make up your own mind armed with as many of the facts as I can find.


Picture
STOP using WHITE vinegar TODAY!
_Question: What the HELL is the FSA & the FDA doing, allowing human beings to ingest a synthetically produced, petro-chemical derived ANYTHING in terms of foodstuffs? I mean EEEOOOOWW!

And another great question - why isn’t this stuff shown CLEARLY on the label? Why do you have to be freakin' Sherlock Holmes to find out that what has been touted as the “Greener Cleaner” is possibly the farthest thing from?

I can’t answer those questions for you or I & I know that FSANZ can’t be BOTHERED answering those questions either. I contacted them several times during research for this too.

But, what I can say is this - you can replace the white vinegar cleaner with lemon juice (KNOWN to be naturally occuring!) for its bleaching properties & softening of fabrics (its the acid that softens fabrics by removing the build up of soap scum from the fibres). You can use apple cider vinegar for around the house cleaning. You can use white WINE vinegar for windows - I just dilute it 1 : 5 and use it in the same way as I did for white vinegar. Works just as well!

There are other vinegars (some white vinegars are also but not many of the el-cheapos from what I've seen) that ARE in fact brewed or fermented and ARE in fact, greener cleaners.

Sorry to be the bearer of more bad news... but its good to know what's what, right?

Love and frustration,
The Eco Mum xo

P.S. I copped a flogging over this article, as you'll see below in the comments. This blog is a green living, green loving, all things natural, NO THINGS chemical blog. Please understand that when I am writing, I am writing from that angle and for that audience - not the wider chemistry circuit, the petrochemical companies or for those who delight in the advances of the petrochemical world. If you are here, reading this try to appreciate that we don't all relish living in a world where we can not escape from pollution - there is just no where to hide from it anymore. Also, please try to understand that as parents, some of us are less than thrilled that we can not protect our children from the onslaught of chemicals affecting the health of their tiny bodies.

I did my very best to find out all I could on this issue & present here. It was not well received by some members of the general public. It was not an easy task and involved months of collecting information, contacting manufacturers, the FDA, FSANZ and a number of other companies - all of whom ignored me.

As requested by some of the readers from the general public, I have however altered the statements which have caused such upset amongst you. I hope that this new edited version is more "palatable" for everyone :)

 


Comments

Excellent investigative work! And a very informative post! I really need to look more into this!

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M. Smith
01/08/2012 21:54

Please disregard the previous post from me...somehow part of it was missing...

My thoughts after reading this blog: I wonder if this would sound as scary if she had studied chemistry.... Just curious. Did you know that the number one doctor-recommended RX for heart attacks in the minutes following an episode is none other than salicylic acid? Aspirin? The word ACID should not be scary in and of itself. Ethanol is the same thing as Jack Daniels (sort of), and chemically, HOW one arrives at a chemical substance does not make it LESS of a substance that it claims to be....It either HAS the formulation to be acetic acid, or vinegar, or it doesn't....which would mean it would be some other compound. I don't know. I am all for being informed, but it's the interpretation of the information we find that we must pay due diligence, and truly mull over. The connection to the petroleum industry makes me feel as if I should be wary .... Is this to mean that we want NO oil industry? You know another source of ethanol, ... CORN....the Government subsidizes corn EVERY DAY, from farmers forced to buy Monsanto Round-UP genetically altered Corn seed for their crops, and puts corn-derrived ethanol in our gas pumps...so that you will get 10% ethanol in your tank in lieu of true petroleum, making cars less energy efficient. Who shares largely in that profit? Monsanto, but your STATE will tax all of it as if you are getting 100% vehicle Petroleum / Fuel. Not 90% of it. At least they require stations to place a sticker on pumps informing you of that fact....that you think you are buying gas at a better price at the station around the corner from your work than the one by your home, because the cheaper one actually has corn-additives in it. Is this a good thing? You know....Socrates advocated for moderation in all things. (Haha...not like this reply, I'm afraid....so bowing out now......)

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01/08/2012 22:13

Interesting points you've raised there... seriously!

The point of the post is NOT the "acidic" nature of anything, be it naturally occuring or otherwise.

The point is that, after contacting every MAJOR manufacturer of WHITE vinegar in Oz no one could offer assurances that their product was natural.

And here we all are, us Eco Mums who are busting our guts to do the right thing by the environment, not use chemicals in our homes and we are being led to think that WHITE vinegar IS natural, and ISN'T chemically derived in anyway.

That isn't true! And no one has yet been able to offer any assurances otherwise... why is that?

And why is it that some labels say "distilled" or "fermented white spirit" or whatever and others say "acetic acid - 5%" and still others say "distilled acid"?

Why is it that posts like this even have to be written? Its a joke! Why is labelling so ambiguous that you can't even ever know for sure if something is naturally derived, man made or synthetic?

Until I personally know for sure where the white vinegar comes from and how its made, given what I've been told, read and found out regarding general manufacture of "synthetic alcohol and acetic acid" I won't be using it in my home.

And corn - Monstanto - all I can say to that whole arrangement currently underway is "ERK". The whole thing makes me sick to my stomach & worries me greatly, watching from the sidelines. And yes, I know alcohol can be made from corn... and rice, and potatoes, and fruits and... lots of things. I just wonder what WHITE vinegar is made FROM and NO ONE can tell me - manufacturers don't or won't, distilleries won't, plants won't... what's the big secret then?

Readers can do what they like - I don't mind either way; at least someone has taken the time to sit down, do as much research as was humanly possible with companies blocking efforts left, right and centre and write their findings. Its up to readers to deduce from that what is right for their homes and families.

This is after all a blog for Eco-Mums.

If only one thing happens as a result of this it is people question before they buy.

And don't even get me started on Aspirin...!

Betty
01/09/2012 01:54

My bottle of DYC white vingegar says it is naturally brewed. Says under the ingredients White Vingegar (brewed from fermented spirit derived from milk). It says nothing about any acteic acid. So I'm guessing this is one of the good ones? NZ made.

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01/09/2012 02:03

Hi Betty!

Ah! You are SO lucky! You've got what appears to be a good one... its got ingredients (other than "acetic acid" or "distilled white spirit" ) listed... that's a very good sign :)

My rule of thumb now is that unless it says grain / milk / fruit / vege or SOMETHING than I don't buy it or use it...

You've done well. Post the brand here so that people in NZ can buy it too :)

And thankyou for posting! :)

11/18/2011 13:51

Thankyou! Took me a while to get it all ... cheeky little White Rabbit didn't leave very much of a trail to follow!

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11/18/2011 14:00

The one thing you have to be careful of is that a lot of sites say that its created from fermentation... yes, it is, in some countries. Just not ours and not in USA either. They admit that its synthetic & decided it was safe anyway... but yeh, read up on it. Quite amazing... in a scary way!

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Abbie
11/18/2011 14:34

What are the requirements for something to be classified as 'food grade' then?

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11/18/2011 15:03

That's a REALLY great question!

You would think it would be something common sensical like "Naturally occuring, non-toxic, non-irritant" etc...

...but if that were the case then acetic acid would NEVER be allowed to be consumed by humans!

The FSA and FDA standards (which are basically identical) are very loose & appear to be more concerned with votes & funding electorate campaigns than with human safety.

Why else is BPA still allowed to be used in plastics containing foodstuffs when science has shown it to leach into foods & liquids?

You can check out standards on the FSANZ website if you like - be prepared for a LOT of ambiguity: http://www.foodstandards.gov.au/foodstandards/

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Karli
01/09/2012 04:07

Scientifically acetic acid = white vinegar = acetic acid, no matter how it is made. It is completely false to assume that acetic acid is necessarily the synthetic version of the distilled product; that would be like arguing that dihydrogen oxide is bad for you whilst water is good. One is a scientific name and one is a common name.

Also, "naturally occuring" is not part of a common sense definition of what is food grade. Just as the other two words you suggest are not always true for edible, safe products, Naturally occuring things can be toxic. Toxic things are consumed all the time as part of remidies for ailments and what is toxic to one body may not be so to another body; this is just as true for irritants. Most people love eating mangos but they irritate my system so that I end up with a rash, yet they are still considered by most to be "food grade", as are peanuts, prawns and a whole lot of other things.) My point is that there is no "common sense" definition that suits everyone and scientists have to debate to find a definition that they find works best for most.

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sara
01/10/2012 05:00

I agree with Karli.

11/18/2011 17:16

thanks so much, for doing such thorough research. Can't take anything for granted these days, reminds me to question everything!

Eleanor

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11/18/2011 21:57

what percentage of "white vinegar" is distilled grains v. acidic acid? I went and checked the label on my bottle (generic Kroger brand) and it DOES say "distilled" There are no ingredients listed. So can I be sure this is made from grains?

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01/09/2012 00:49

Not really... a source I read called Vinegar: Its History and Development by HUBERT A CONNER says: "While white distilled vinegar can be made by the acetous fermentation of ethanol from any source, almost the entire production of this vinegar
in the United States is derived from synthetic ethanol. In England the term “distilled vinegar” is applied to a distillate of malt vinegar, whereas in the United States the word “distilled refers to the ethanol used as a raw material; the vinegar itself is not distilled"

Its so frustrating - this path is all over the place!

So, from my POV, I used up what I had in my pantry then switched to natural forms that I KNOW are naturally made (i.e. apple CIDER vinegar, white WINE vinegar etc) because then I don't have the guilts using something that isn't all that good...

The other issue is that acetic acid is harmful to marine life - but which kind??? The "natural" kind as in all vinegars or the synthetic kind? I can't find that out - I keep asking and asking and not getting responses. Grrrr...

Sorry I can't be more help but that's what I did - used it up then switched, to be safe and sure :)

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Kristin
01/09/2012 06:53

"The other issue is that acetic acid is harmful to marine life - but which kind??? The "natural" kind as in all vinegars or the synthetic kind? I can't find that out - I keep asking and asking and not getting responses. Grrrr..."

The natural and synthetic kinds are chemically identical. You may not be getting responses to this question because it doesn't make a whole lot of sense.

Roch 503
01/11/2012 16:36

As M Smith stated earlier, it doesn't matter what the acetic acid is made from, it all has the same elemental structure and is the same thing, regardless of whether it's made from grain or petroleum based products. Therefore, IF studies have shown that acetic acid is harmful to marine life, it doesn't matter the origin of the acid.

11/19/2011 08:34

Good research and thanks for getting the word out there. I have made a vinegar just from fruit scraps that I use for cleaning (and even eating) and it's almost free because you make it from apple cores and such. It's not as high quality as apple cider vinegar but still ok for eating and perfect for cleaning. Thought you and your readers may be interested in this: http://thenourishingcook.com/how-to-make-fruit-scrap-vinegar/

Reply

Wow, this totally bums me out to read. Thanks for such a thorough look into it!

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Mary
11/19/2011 14:18

Um, stomach acid is corrosive too. It's dilute hydrochloric acid. acid

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Emma
01/11/2012 01:35

Exactly!! Thanks for saying that Mary, I was going to say the same thing.

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11/19/2011 14:30

You're very welcome Eleanor! I am a bit of a research & learning junkie so happy to pass on what I know.

Did you see the posts about plastics & silicones & the myth busting there? Well worth a read too! :)

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11/19/2011 14:32

I wish I could say 100% either way for you on that one... I really can't tell you!

I would ring the company & ask them where they get their vinegar supplies from or how they are made in writing. Even that, these days, isn't a 100% guarantee but if they lie you can get them on false advertising.

Wish I could help you more - labelling is SO ambiguous these days. You have to be Sherlock Holmes to find out anything!

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11/19/2011 14:33

Thankyou Kim! That's very helpful. Do you mind if I share the link on my Facebook page? I've heard a few of my Eco Mummas do the handmade stuff at home with great success! Will have to give it a try now me thinks :)

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11/19/2011 14:34

@Rebecca - yeh, I can understand. I felt the same when doing the research. Makes me so cranky & almost helpless. No matter how hard you try there's always something else to be done to protect your home & the planet. Us humans have made a royal mess of things!

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11/19/2011 14:35

Indeed it is Mary - I don't know many who eat it on their fish & chips though! ;)

Pretty sure the warnings on that are extensive & its not to be handled or used around the house... so why should a diluted product of the same (or similar) be allowed to be eaten??!!

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Marg
11/19/2011 21:40

(not "Mary" as I inaccurately typed earlier)
Why SHOULDN'T vinegar be allowed to be eaten? That's what saurkraut is. Naturally made vinegar. Salt will corrode metal with the right concentration, by your logic, that would mean we shouldn't eat salt. Which is all over our skin after we sweat.
Plus,
1) my Heinz white vinegar says its distilled.
2) My apple cider vinegar (USDA organic, from trader joe's, as if that matters) says nothing about distilled.
3) Petruleum jelly (a primary ingredient in many lip balms, often called "vaseline") is derived from, guess what, petroleum, and even the Environmental Working Group rates it as a "zero" in terms of toxicitiy (or is it a "one" because there is a snowball's chance in hell it could be contaminated with some heavy metal--water can be too.)
4) a molecule, is a molecule, is a molecule. Acetic acid is a molecule. If its mixed with water, its that molecule, plus another chemical: H20. Whether its made in a lab or distilled or extracted from my fermenting compost heap, its the same molecule. There could be contaminants that are a problem. Or there could not.

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11/19/2011 21:52

Hi Margo :)

Not sure if you read the post all the way through, based on your comments.

My issue (and a lot of other people's) is NOT that vinegar is corrosive. The fact that it is mildly corrosive is what makes is effective. I regularly use lemon juice for its acidity & salt for the same... as you'll see in the blog post.

MY issue is the way it is produced - using iridium as a catalyst, which is mined from the earth's core & using petrochemical substances to create the acetic acid. This is then watered down at a ratio of 5% acid to 95% water, resulting in "white vinegar".

I am glad to hear that your vinegar label says "distilled". Alot of others don't say that - they say only "acetic acid - 5%" & that's it.

The purpose of the post was to go deeper into the idea of using acetic acid based, non-distilled white vinegar as a cleaner for those of us who prefer chemical free households for our children. White vinegar is touted as a greener way to clean when in actual fact, there is nothing green about using some types of cheap white vinegar (which is what is usually bought when cleaning).

Apple cider vinegar, white WINE vinegar, rice vinegar, malt & brown vinegars, balsamic, red white vinegars are ALL distilled grains, fruits or wines and I believe (and have said so in the post) safe for use & consumption.

The aim of this site & therefore this post is to provide the FACTS about how things are really made so people can make informed choices. Alot of the Eco Mums on here, like me, don't want chemicals in our lives where we can avoid it.

Sadly, we live in a world where it isn't totally avoidable but we do our very best to live naturally & chemically free where we can. Using non-distilled white vinegar is not living chemically free - hence the post.

Personally, I prefer not to put anything petro-chemically derived near my family; their skin, stomach or even have it in our housedhold so vaseline & the like doesn't even get a look in.

Read more here: www.chemicalfreeparenting.com.au because this is what I & alot of other people on this site stand for but of course, each to their own! :)

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Marg
11/20/2011 06:40

I too prefer to avoid exposing my family to toxic substances, hence, my interest in your post. Your emphasis on the corrosive nature of acetic acid implies it is one of the reasons it should be avoided. More soon.

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01/08/2012 21:36

Hi Mary,

No, not at all. Citric acid is corrosive to a certain extent - especially in higher concentrations. We have hydrochloric acid in our guts to break down food!

The purpose of the post, and the reason I personally choose to avoid white vinegar from now on is that there are NO assurances, not at all with any manufacturer that white vinegar is made naturally using natural substances.

Now, most companies can't WAIT to rave about how their products are natural - why not the vinegar companies? Does that mean they are different & don't want to "green wash" like everyone else or that they aren't infact natural produts at all?

Until I get assurances from a manufacturer about how their white vinegar is made I won't be using it... but that's my personal stance on this issue.

I don't mind what people do in their own homes! :)

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Jim
11/21/2011 05:54

Acetic Acid is responsible for the sharply sour taste of vinegar in BOTH fruit-derived and petroleum-derived vinegars. It is inflammatory, especially to nerve tissue. Substantial amounts of it have been known to trigger aggressive behavior in individuals otherwise not known for that.
So I choose not to use it internally regardless of source. Knowing the supposed watchdog agencies don't mind a bit if it's petroleum-derived though, is valuable information. Thank you.

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01/08/2012 21:38

Thanks Jim! And you're welcome!

www.bodyecology.com talks about health benefits of ingesting apple cider vinegar for gut health. What do you feel about that - is it a safe practice from your point of view?

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Sarah
11/24/2011 01:10

hi Eco mum. I use the cheapest white vinegar for cleaning floors and for deterring ants and stopping the dogs from peeing in certain places.
What about washing vegetables in a diluted 1 to 2 tablespoons of vinegar to a bowl of water? How safe is that ?

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01/08/2012 21:39

Personally (and I am not saying you have to do this - its just what I do) I use either lemon juice or white wine vinegar or rice vinegar for food stuff... to be safe :) Until I know for sure, I'd rather not take the risk.

These manufacturers have a way of making the dodgy parts "disappear" and it comes back to bite us over and over again - all through history. I dont' believe now to be any different...

But you do what you feel is right for your family :)

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01/09/2012 13:14

One more thing to add to the debate; vinegar changes the pH level of water. Don't use it in large quantities as does bicarbonate We deal with thousands of people with black water, bio systems, and grey water systems and they are advised no to use either. Kills all the bacteria needed for breaking down waste. Most people use it for cleaning because it's cheap - we talk to thousands of people and using it because it's 'green' is low on the list. In Victoria we've had prolonged years of drought. I always worried about the amount of water to rinse away the dreaded white streaks bi carb and vinegar leaves

11/24/2011 01:35

Hi Sarah :)

Erm... I would switch over to something like apple cider or white wine vinegar or rice vinegar for the fruit & vege washing.

We use bulk lemon juice in place of our white vinegar now. The use of iridium in making white vinegar (the acetic acid type) surprised me.

If it says "distilled" anywhere on the bottle, its been distilled (funnily enough LOL) so its also ok :)

You can even make your own if you wanted - off vege & fruit scraps in a tub under the house or in the laundry or something :)

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Jade
01/08/2012 23:57

I completely see the point of your postm but one thing in this comment is irritating me, All vinegar, regardless of how it is derived is acetic acid, not just the iridium catalyst, laboratory version.

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01/09/2012 00:53

Hi Jade,

Yes, you're right - that's true. The main issue is the PRODUCTION of said acetic acid - is it "naturally" done (i.e. oxidation / fermentation / distillation) or is it done synthetically as it appears to be for just the white vinegars?

Who knows!? Been trying to find out 100% either way & I can't... I think I've got it then see another source whereby it says its produced synthetically (using for example ethyl acetate and ethyl alcohol to make it...hmmm... ethyl acetate is in nail polish etc - I don't want to be eating that!)

The annoyance for me is the labelling - its not clear WHAT EXACTLY it is. And it should be. We shouldn't have to even be doing this much research to have some vinegar on our fish and chips or use it to clean our homes.

Its a joke.

*end of rant* LOL :)

11/24/2011 01:44

Hi Jim,

I didn't know that about the other kinds of vinegar as well - thankyou for sharing :)

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Catherine
11/29/2011 07:22

Wow. That was a great read! Thank you for sharing all your research! The brand Heinz recently ran an ad campaign based on their white vinegar coming from grain not petrochemicals. That's what we use at my house now. : )

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01/09/2012 00:54

Hi Catherine,

Are you in the States? We didn't see that here. That's SO good to know - thankyou!!! I shall pass it forward...! :)

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11/29/2011 12:12

WOW! Thank you so much for sharing that!! After reading this I ran over to my HUUGGGE jug of vinegar..mine says distilled (watered down to 5% acidity)Sounds like it's still using chemicals???? WDYT?
however, I have always followed the rule white is for cleaning, apple is for eating Thanks!

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11/29/2011 13:50

I was starting to get scared...

But the bottle on my shelf says "Distilled White Vinegar" (Heinz). It indicated that it is made from fermented grains, then diluted with water to a uniform level of 5% acidity. That's different than saying it's "5% Acetic Acid".

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Emma
11/29/2011 16:23

Hi EcoMum!

This is very interesting research. My big cheap bottle of Coles brand white vinegar says "vinegar brewed from fermented spirit" and states the ingredients as "water and vinegar" Should I be looking at alternatives?

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karli
01/09/2012 04:21

In terms of what is beng argued her ie natural verses man-made/synthetic, fermented means that it must have come from a natural source that the fermenting bacteria are able to consume in order to produce the alcohol in the spirit that is the base for the vinegar. This is then further converted to vinegar. ie There's a fine line between fermenting fruit to make wine and fermenting fruit to make vinegar. It's really just a case of getting the bacteria mix wrong. The description sounds natural to me. The fac that water is added is not an issue it just means that the vinegar has been diluted so that it is almost the exact same concentration every time you by it. As it's a natural process you can't guarantee the exact outcome each time, so they water it down to the same point.

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Andy K
11/30/2011 06:10

"Acetic acid is synthetically produced & petrochemically derived alcohol made in a lab watered down for “safe” human consumption"...Jan, we have stronger acid in our bodies. Historic acetic acid production was not 'petrochemical' based, but rather came from the wine that Eco Mom spends about 2 words talking about out of 1000. Acetic acid, like any acid is biologically sound because through dilution, it tends to water. Better than nitrates/phosphates that are being poured down our drains daily.

To say that it is petrochemically based seems spurious. Because oil was abundant (and is), the easiest way to get to CH3-COOH was to subtract a little from ethyl alchohol. This does not mean it is dangerous - acids will dilute themselves when added to water. Neither does it mean its use is unconscionable - we could synthesize any organic compound (acid,alcohols, alkanes/kenes/kynes, ketones, aldehydes) from petrochemicals. That we can put one product in and get so many out just means we're using more and more parts of the buffalo. Petrochemically synthesized is another word, that sounds a lot worse, for conservation-minded. Instead of pumping this product back downhole, or burning it off, we have used it to ... fill in the blank. Since it is a byproduct of an addiction to oil, the terrible way to go would be to flush it back down the toilet without finding a suitable use for it. Anyone who wants to swear off of the whole oil addiction we suffer from had better not use a computer, a car, a furnace, plastic, telephones, or a myriad of other devices/gadgets. Or just use white damned vinegar on the floors not because its amazing (http://www.kitchenproject.com/history/Vinegar/index.htm), but because its simply better than the alternative.

Reply
Phoenix
01/08/2012 16:46

"Acetic acid = made in a lab. Petrochemically derived."

Whoa....that's not true at all. Not all acetic acid is synthetically produced. Acetic acid is also biologically produced as a product of fermentation. It's produced by bacteria. Acetic acid is in all vinegar, synthetic or not. Yes, it can be made synthetically, but your basing your hypothesis on whether or not white vinegar is made with acetic acid or not. Every vinegar has to have acetic acid in it. White Wine vinegar, corn vinegar, malt vinegar, apple cider vinegar, barely vinegar...they all have acetic acid.

The good point is to read the labels. There ARE white vinegars on the market that are made with petrochemicals. Avoid those if you'd like. But, there ARE white vinegars (not to be confused with white wine vinegar) out there that are grain distilled and their acetic acid comes from the fermentation process and is not synthetically derived.

Reply
01/08/2012 21:15

Yes, Phoenix is correct - there ARE some vinegars that are safe - as it says in the post. And yes, reading labels is really the only way to know... especially when I contacted the major manufacturers in Australia and NONE could offer their assurances that their vinegars were made naturally (distilled alcohol).

Until I get that assurance from a manufacturer (some of them were contacted 3 times and no response was received at all) I won't be using any white vinegar in my home.

I am not saying this HAS to be or SHOULD be the case for everyone - I am saying that this is what I am doing in my home because I refuse to support the chemical industry by buying its products in any shape or form, be them derivatives or otherwise.

Each to their own - read labels, be sure :)

Reply
Phoenix
01/09/2012 08:21

I know you said some vinegars are safe. I'm saying that some WHITE vinegars are safe. You still have the line:

"Got that? Distilled = fermented grains with alcohol like rice vinegar for example.

Acetic acid = made in a lab or petrochemically derived. "

...in your post, which is entirely untrue. Yes, acetic acid can be made in a lab or petrochemically derived, but that is NOT the case for ALL acetic acid, as your statement implies.

I can't help you as far as what's in Australia. It's annoying that you can't get the whole story from these companies. I can tell you that grain distilled white vinegar is VERY easy to get in my area of the USA and is usually cheap.

I'm with you on the fact that we need to check labels and be educated, but you lost me on a few points in your post. It's not all or nothing. You say you are simply sharing what you do in your own home, but your post comes off as an indictment towards those who use white vinegar. I know you were modifying some of the condescending tone...

01/08/2012 19:36

Oh good grief...could you get more paranoid? I really think that chemistry should be a required subject before high school graduation. Just an eensy weensie bit of knowledge might help a bit.

My WALMART brand white vinegar has as the listed ingredient "distilled vinegar." By your definition then, it is okay, right? But wait...on the other side of the bottle it says "distilled with water to 5% acidity." It doesn't say "acetic acid" anywhere on the bottle, but as is pointed out by another poster...acetic acid is simply the name of the compound, it doesn't indicate if it was naturally derived or syntheticly derived.

"Acetic acid [DOES NOT] = made in a lab" any more than "dihydrogen monoxide = made in a lab" For those who are not in on the joke, "dihydrogen monoxide" is H2O...or water. Which yes, can be the by-product of a chemical reaction in a lab...or a chemical reaction in the atmosphere. And guess what? There isn't any difference between the H2O made in a lab and the H2O made in the atmosphere.

"The second (although not widely used as its expensive) way of producing acetic acid is through the process called “acetaldehyde” (sounds like formaldehyde... does that give you confidence this is healthy stuff?!) "

Oh, wow. Just wow. This makes my head hurt.

First of all, "acetaldehyde" is not a process. It is a compound. Note that I did not call it a "chemical," because that scares the chemically illiterate masses. The truth is that acetaldehyde, like many compounds, is naturally occuring (from Wikipedia "Acetaldehyde occurs naturally in coffee, bread, and ripe fruit, and is produced by plants as part of their normal metabolism.") and can be produced synthetically.

That "acetaldehyde" and "formaldehyde" have the same suffix is not so important as is implied. They both have that suffix because they both contain the "aldehyde" group RHC=O ("R" is a place filler, where different organic groups can be...and "organic" is not in the sense that is being described in this post, it is in the chemical sense of compounds that are carbon containing or compounds that aren't carbon containing). The difference is that formaldehyde is H2C=O while acetaldhyde is H3CHC=O. The difference between them is much like the difference between carbon dioxide and carbon monoxide...one is a normal biproduct of human respiration while the other is a deadly poison.

Now whether the process to process acetic acid is producing some environmentally unfriendly stuff is an entirely other discussion. But I can tell you from having worked inside of one of the largest speciality chemical companies in the world for 12 years--6 of them in research and 6 in Environmental, Health, and Safety (EH&S)--that the large chemical companies in America are actually amongst the safest and most environmentally responsible of all companies in this country and perhaps the world. It wasn't always that way for sure. But in the mid-late 80's and especially going into the 90's, the chemical companies realized that they needed to clean up--that it was good for business. And they did it in a serious way. The media just doesn't cover that because it doesn't sell newspapers or magazines.

Ironically, I took a job as an EH&S manager at a large newspaper after working at that chemical company, and found it to be a HUGE culture shock. They really weren't as concerned with the issues that I cared so passionately about. I called another of my co-workers who had also taken a job with another company in another industry, and he reported the same thing--huge culture shock. The things we had been doing for EH&S 10 or 15 years prior at the chemical company were hard to push through and get implemented at our new employers. Fortunately for me the environmental impact of the processes at my company weren't so big (it was the employee safety & health issues that kept me awake at night). My former coworker though was working for a battery company, and he was getting slammed on all 3 fronts. Poor guy.

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01/08/2012 21:34

I greatly appreciate your insight into this issue - it is clear you can offer a great deal of helpful information & perhaps shed some light here. I spent months researching the content for this post, contacted ALL major manufacturers here in Australia for assurances that their product was naturally occuring, of natural substances or used "natural" processes (distillation / fermentation) without synthetic "involvement" in anyway.

No one responded at all. No one offered assurances. Of all the vinegars available in Supermarkets (not specialty ones like the organics etc) none of them say "100% natural". To me, if a product is naturally occuring or uses natural processes, most companies can't WAIT to play the "green card" or "green wash" for more sales.

Are WHITE vinegar manufacturers different in some way? I think not. I suggest alternatives that I KNOW to be natural; apple cider, white wine, lemon juice. I will be using this alternatives in my home until I get the assurances from manufacturers that their products are natural. I am sorry if you disagree with that - its just my preference for how I run my home.

So, whilst I appreciate some of the interesting content in your post, I don't appreciate the degrading opening line directed at myself or readers nor do I appreciate the sarcasm so easily detectable in your response.

You are welcome to respond to this, politely, respectfully and debate the POINT in any way you choose.

I do NOT permit ANYONE to insult me or my readers in anyway, in any comment, post, thread or otherwise.

This is a respectful group of concerned mothers (and fathers) attempting to do right by the world and by their kids. If that makes us paranoid in your book, then so be it. I myself prefer to employ my own version of the "Precautionary Principle" rather than take things at face value where money was and is the main driver.

Any responses posted on this site are reviewed and the author given a chance to address the written shortcomings or what I hope to be oversights... after that, they are deleted and the user is banned.

There is enough garbage going on in this world without this blog being dragged down by disrespectful, impolite or critical comments.

As I said, thankyou again for your insight - I myself found it fascinating & would happily discuss further if its not laced with so much sarcasm next time around.

Reply
01/08/2012 22:37

As is pointed out by another respondant...your own original post is laced with sarcasm...thus I felt the tone of my post was very much appropriate. That said...I will try to dial it down a bit.

I checked the references that you gave at the end of your post to find the process for making vinegar that you describe, and none contained it. Do you have specific references for the process of making vinegar that resemble at all what is presented in this blog? This is what I find for the process to make vinegar, which does contain information about commercial scale production: http://www.madehow.com/Volume-7/Vinegar.html

Further, I specifically found information on the FDA website that indicates that food products that are expected to contain vinegar, such as pickles, may not substitute acetic acid, and diluted acetic acid may not be sold as "vinegar" because acetic acid is a component of vinegar, and other components are necessary to truly make it "vinegar." http://www.fda.gov/ICECI/ComplianceManuals/CompliancePolicyGuidanceManual/ucm074577.htm

The quote you use about the majority of vinegar being made from synthetic alcohol is from the 1960's at best (possibly earlier, it isn't really clearly referenced in the document) and is actually quoting an OPINION from the U.S. Alcohol, Tobacco and Firearms Division, Internal Revenue Service. I'm not sure why they would be expected to have accurate information on this, or why we would consider the situation from so long ago to still be in place.

01/09/2012 00:45

Sorry - for some reason it won't let me reply to your reply... its being difficult :) And yes, you’re right – some of the language in the post is sarcastic and inappropriate – it has been modified. Thankyou for pointing that out :)

The challenge I have with what I read on the FDA site (your second source mentioned) is that it appears to contradict the policy outlined in the post... my question therefore is why is that? We should be able to buy something knowing what it is and what it is NOT and we can’t because the FDA (and our FSANZ who copy the FDA in just about everything) are ambiguous with their policies.

It is my belief & experience that this ambiguity means that loop holes can be found and exploited.

My post refers to some white vinegars being “distilled” which APPEAR to be ok… and others that are labelled as “acetic acid” which, based on supposed labelling requirements means that those particular brands are in fact, acetic acid – watered down to 5% dilution (“acetic acid – 5%” is common on labels here in Oz). But no reference is made to which type - the "natural" or "synthetic" kind which is the point of my writing the post in the first place - i.e. "You don't know, I don't know! Play it safe until you know for sure because it SAYS this on some bottles & this is standard production of this particular thing" etc etc.

Also, yes, I had read the source you quoted for making vinegar, among a ZILLION others just like it and was almost totally satisfied until I found these sources also:

1. Presence in foods acknowledged here (listed as environmental pollutant) but not specified as to which TYPE is in foods (naturally occurring or synthetic): http://www.npi.gov.au/substances/acetic-acid/source.html

2. http://www.comlaw.gov.au/Details/F2011C00827 - This one concerned me a lot because it SAYS that the labelling must be clear. From that, one deduces that acetic acid is in fact that – acetic acid (of the chemical form not the “distilled” form) because, legally it has to say distilled…apparently. Again, this is ambiguous… but not a long bow to draw if its labelled “acetic acid” to think it is, in fact, acetic acid of the synthetically produced variety especially when there is policy with FDA in existence saying its ok for it to be synthetic under certain guidelines.

3. http://chemical.ihs.com/WP/Public/Reports/acetic_acid/

Most of my other sources I had to buy / pay for so didn’t list them because they’re useless unless you want to fork out quite a bit of money… I wanted to get to the bottom of this so I did pay for them.


4. Advances in the use of various catalysts for production of acetic acid: http://www.sciencedirect.com/science/article/pii/S0926860X01008006 (have to purchase) and here http://www.sciencedirect.com/science/article/pii/B9780123739445001280

5. http://chemical.ihs.com/WP/Public/Reports/acetic_acid/

6. This was the most informative (its $35 to read it though…) http://onlinelibrary.wiley.com/doi/10.1002/14356007.a01_045.pub2/abstract
It explains the process known as “Acetaldehyde Process” in great detail and outlines uses for acetic acid after industrial production including; ice cream, synthetic caffeine, natural gums and as an additive in some foods. It did mention organic synthesis of acetic acid but didn’t state one way or the other which type of acetic acid is used across the board in foods or as condiments – the natural kind or the other kind…?

It DOES make reference to vinegar being produced by fermentation processes but other sources say otherwise. It also goes on to say that 11% of acetic acid produced is used in acetic acid esters (NOT natural) as additives in foods. However, as you rightly point out the acetic acid shouldn’t be being put into our pickles or whatever as an additive in place of vinegar etc because it’s not really true vinegar (other things are required to make it so yaddah yaddah).

7. http://www.sciencedirect.com/science/article/pii/B012227055X012517 This sources states over and over that vinegar is oxidation (as opposed to fermentation – very exacting source this one was) however it also says “At the present time, vinegar is still produced micro-biologically from a mostly natural alcoholic solution, but can also be produced by dilution of acetic acid.”
BUT WHICH KIND? The natural kind or the not-so-natural kind?

8. I also bought and read a great article called Vinegar: Its History and Development by HUBERT A CONNER. It was a very interesting read indeed & to quote: “While white distilled vinegar can be made by the acetous fermentation of ethanol from any source, almost the entire production of this vinegar
in the United States is derived from synthetic ethanol. In England the term “distilled vinegar” is applied to a distillat

01/09/2012 00:57

Part Two - it cut me off LOL

8. I bought and read a great article called Vinegar: Its History and Development by HUBERT A CONNER. It was a very interesting read indeed & to quote: “While white distilled vinegar can be made by the acetous fermentation of ethanol from any source, almost the entire production of this vinegar
in the United States is derived from synthetic ethanol. In England the term “distilled vinegar” is applied to a distillate of malt vinegar, whereas in the United States the word “distilled refers to the ethanol used as a raw material; the vinegar itself is not distilled”. It also goes on to say that most of the white distilled vinegar production uses ethyl acetate and ethanol of a certain concentration. Ethyl acetate is used in nail polish etc – not loving that I’m meant to be ok (so is my daughter) eating something made using this.

It goes on further to say: “…This method cannot be used to determine whether the acetic acid in a food was produced chemically from a fossil fuel or whether it is vinegar produced from synthetic ethanol by Acetobacter….. Inherent variations in the materials undergoing analysis and in the method of analyses make it impossible to detect a moderate adulteration of, say, wine vinegar with acetic acid or with white distilled vinegar from fossil fuel.”


Yes, some types of white vinegar (one would have to ASSUME because no manufacturer will say one way or the other on the record) say on the label that they say “distilled”. But according to the sources above that doesn’t mean the VINEGAR itself is distilled just that it contains alcohol… so unless it is actually distilled itself, at least from my perspective, it’s still not naturally occurring, not naturally “made” or created and therefore not quite the greener cleaner we all thought it was.
The FSANZ wouldn’t answer my frequent emails and letters (surprise surprise – nor did they about BPA use in food stuffs containers) nor would the touters of “acetic acid” labelled products -- most annoying. I felt I didn’t have much choice but to go ahead and post as a forewarning to check labels or stop using it until we know better.
Having said all of that, if you can get confirmation from ANYONE (FSA, FDA, manufacturers) about this one for all of us, PLEASE DO because white vinegar was invaluable as a cleaner… I just don’t feel right using it if it’s not naturally derived or made using natural processes… that’s part of what I do on this blog & site; is offer natural alternatives to chemical “solutions” or in this case, problems. :)

01/09/2012 01:01

And yes, I saw your link to Heinz - its great to hear! Apparently they did an advertising campaign (I assume in the States coz I didn't see it here in Oz) assuring people that they're vinegar was not made from petrochemicals - thank GOD!

But, does that mean that others ARE??? That's what I want to know, for sure, 100% for sure... 90% isn't good enough for me anymore.

They say "The dose makes the poison" but from my POV any dose of any chemical is poison enough. The body burden of myself and my family I take very seriously... Until I know for sure, I won't be using or recommend using it (except Heinz of course though don't see that here in Oz much...)

:)

Jennifer Davis
01/08/2012 19:44

I don't have time to read all the comments but I am a little confused. I buy Distilled White Vinegar (diluted to 5% acidity). Is that what this is about or is what I use safe?

Reply
01/08/2012 21:23

Hi Jennifer!

Sorry about all the confusion re: the postings from others.

From my POV (and you can make up your own mind) I contacted every major (and a few of the minors too) manufacturer of white vinegar in Australia asking them how their product is made & could they offer assurances as to it being natural processes (fermentation / distillation) as opposed to synthetic compounds, processes or otherwise.

No one, not one company came back saying "Ours is 100% natural!" Nobody! I contacted them all 3 times (some of them more) and no one came back at all.

So, regardless of the "chemistry" outlined above by other posters whom I will address in another response, until I get ANY assurances from ANY WHITE vinegar manufacturer that their product is produced naturally without synthetic additives or involvement I will NOT be using it in my home.

I have a personal issue, a moral obligation NOT to support companies that produce synthetic chemicals for human consumption. I am dead against this and go to great lengths in my life to avoid supporting these companies by buying their products.

That is my personal opinion, always has been & others can do as they wish.

Fact remains that the process of making white vinegar is not clear or able to be found easily - what is that?

Why is the labelling saying "distilled vinegar" on one product, "acetic acid" on another unless there IS a difference in how one is made vs the other?

And why is it necessary to have ANY degree of chemistry understanding at all when it comes to buying a condiment for goodness sake?

In my opinion, the ambiguity of labelling around this one product (one of MANY where labelling laws are a joke) means I can't trust it or the manufacturers.

That's how I feel and this post was purely to point out what MY research uncovered and provide as much insight as I could gain for others... fact remains we should not have to be doing this at all.

I buy and use that which I KNOW to be safe. :)

As a general rule, "distilled" SHOULD mean its safer but I'm afraid I can't assure you either way - in the same way manufacturers can't assure me.

Sorry I can't be more help to you - its been hard trying to get ANY information from manufacturers about this at all.

Reply
01/08/2012 22:59

Here is what Heinz has on their website about their white vinegar: http://www.heinzvinegar.com/products-distilled-white-vinegar.aspx

I'll admit I live in Heinz country--the same state as they are located, so I don't know if this is typical across the US. In the grocery stores that I shop at there are only two kinds of white vinegar--Heinz and the store brand. Walmart being the biggest "store" in America...well I thought it was pretty relevant that the Walmart brand vinegar that I have right now says that it is distilled.

Interestingly...the MSDS for Heinz vinegar is almost identical to the MSDS you posted. It doesn't mention anything about how it is made from grain alcohol, and in fact references dilute acetic acid as its primary ingredient...because that is what it is. Note that "dilute acetic acid" is not the same thing as "diluted acetic acid." This is true even if Heinz does dilute the vinegar it produces. Because I'm sure if they get a batch of vinegar that has 10% acid in it...they are going to dilute it to 5%.

01/09/2012 10:18

This reply is to Eco Mum...just can't submit replies past a certain "level" here.

I don't have any conclusive proof of this...but I suspect that most white vinegar in my area is either made by Heinz and just bottled with a store brand on it, or is at the very least made with the same process.

Why do I suspect this? Well I've been unable to purchase gallon jugs of white vinegar for nearly a month. I've looked in at least 6 different stores, and they are all out of stock of both Heinz and the store brands, and the smaller bottles are also in low supply. Ironically enough, yesterday afternoon--before reading this blog post--I asked a store employee why they are unavailable, and she did not know. I sent an e-mail to Heinz last night, I'll post back if I get a reply.

But I think that BOTH the store brands and the Heinz brand being unavailable points to some problem in production affecting them both.

Many of your sources listed above deal with production of acetic acid, and not necessarily production of vinegar. I think something you may be missing is that the bulk of acetic acid that is produced never makes it into the food stream. Your reference #3 (#5 is the same reference) shows a pie chart for acetic acid uses, most of which are not for the food industry. In fact, I suggest that most of the food industry uses fall into the small "other" wedge. A large amount of acetic acid is used to clean machinery. "Food grade" acetic acid would be required when cleaning food processing machinery--I used to use acetic acid to clean the hard water deposits out of my water heating and cooling systems in the lab much like many people run vinegar through their coffee pots to clean them. Acetic acid is also a necessary part of many chemical synthesis processes...for example, I used to use acetic acid in the production of polymers that were being researched for use in computer chips. We used food grade simply because of its purity.

Yes, I've seen acetic acid listed as an ingredient in food products, so I know it is there. Its never really bothered me...being that I've worked with 100% acetic acid when I was in research. I know the conditions under which it is safe (used in small amounts to affect the pH of a food to make it shelf stable), and when it isn't (i.e. I would never pour 100% acetic acid on my salad).

It is entirely possible and correct labeling for a completely naturally produced bottle of vinegar to contain a label indicating that it is 5% acetic acid. Acetic acid is a component of vinegar. Diluted acetic acid does not make vinegar any more than diluted fructose makes fruit juice. Fructose is a *component* of fruit juice, but it is the other trace components in the fruit juice that change it from being mere sugar-water to being fruit juice. The same is true of vinegar vs. diluted acetic acid.

As for the FDA policy on ethyl alcohol...yes, artificial ethyl alcohol is *allowed* for use in food products. That doesn't mean that it is actually used the majority of the time. Yes, I've seen synthetic ethyl alcohol listed in an ingredients list before--on a bottle of cheap wine that a friend brought over to my house. There wasn't a drop of fruit juice in it, and the ingredients were pretty clear about that...as is required by the FDA policy. One really does need to put that quote about synthetic ethyl alcohol to make vinegar in its proper perspective. It was made in the 1960's or earlier...a time when "scientific" was king, and "natural" was viewed with growing suspicion. TANG was considered healthier than orange juice. Women were told that formula feeding their babies was better than breastfeeding, and even given medication to dry up their milk without even asking them if they wanted to dry up their milk. But there have been drastic changes in perception since that time, so I suspect that OPINION statement does not remotely represent reality any more.

As for needing a degree in chemistry to understand food...generally you don't need one. But when you go talking about chemical matters, you should understand them before speaking authoritatively, or trust those who do have the knowledge since none of us can be experts on everything. You mention that ethyl acetate is used in the production of vinegar, and being upset that it is also in nail polish so "obviously" it is not safe for consumption. But ethyl acetate is a synonym for acetic acid! Just because it has usefulness other than as a food product does not make it dangerous. You refer to acetic acid esters as "not natural," but they are naturally occuring in wines (though an over abundance of esters is considered a fault in a wine) and are what give most fruits and flowers their scents. You keep mentioning alcohol in vinegar. There is no alcohol in vinegar if it is produced properly. The alcohol is converted to acetic acid.

Regarding your 7th reference and its question...according to the FDA document that I previously linked to,

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01/09/2012 10:27

Sorry about the double post there! The first time I tried to post I got a screen saying that it hadn't posted... Anyway, here is the part that got cut off.

Regarding your 7th reference and its question...according to the FDA document that I previously linked to, manufacturers can not label a product as "vinegar" if it is simply diluted acetic acid. Now that would not apply to you in Australia (and that may be why you are having trouble getting responses from your local vinegar producers), but it does apply here in America, and is the bottom line. Diluted acetic acid is NOT vinegar.

I agree with you that vinegar made with use of synthetic alcohol should not be considered to be "natural"...but I just think at least based on my observations locally explained above, that most white vinegar in the US that is sold in grocery stores is most likely made from grain alcohol.

I think you owe your readers a correction and retraction of much of the false chemistry and misleading statements in your post. Yes, you made the statements in good faith, but now that multiple respondants have tried to explain your errors, and you can see in other comments that you've got people scared about the safety of their vinegar, I think you should make corrections because this post is being shared on Facebook...and many people who read it will not read the comments, just your original post.

01/09/2012 10:19

This reply is to Eco Mum...just can't submit replies past a certain "level" here.

I don't have any conclusive proof of this...but I suspect that most white vinegar in my area is either made by Heinz and just bottled with a store brand on it, or is at the very least made with the same process.

Why do I suspect this? Well I've been unable to purchase gallon jugs of white vinegar for nearly a month. I've looked in at least 6 different stores, and they are all out of stock of both Heinz and the store brands, and the smaller bottles are also in low supply. Ironically enough, yesterday afternoon--before reading this blog post--I asked a store employee why they are unavailable, and she did not know. I sent an e-mail to Heinz last night, I'll post back if I get a reply.

But I think that BOTH the store brands and the Heinz brand being unavailable points to some problem in production affecting them both.

Many of your sources listed above deal with production of acetic acid, and not necessarily production of vinegar. I think something you may be missing is that the bulk of acetic acid that is produced never makes it into the food stream. Your reference #3 (#5 is the same reference) shows a pie chart for acetic acid uses, most of which are not for the food industry. In fact, I suggest that most of the food industry uses fall into the small "other" wedge. A large amount of acetic acid is used to clean machinery. "Food grade" acetic acid would be required when cleaning food processing machinery--I used to use acetic acid to clean the hard water deposits out of my water heating and cooling systems in the lab much like many people run vinegar through their coffee pots to clean them. Acetic acid is also a necessary part of many chemical synthesis processes...for example, I used to use acetic acid in the production of polymers that were being researched for use in computer chips. We used food grade simply because of its purity.

Yes, I've seen acetic acid listed as an ingredient in food products, so I know it is there. Its never really bothered me...being that I've worked with 100% acetic acid when I was in research. I know the conditions under which it is safe (used in small amounts to affect the pH of a food to make it shelf stable), and when it isn't (i.e. I would never pour 100% acetic acid on my salad).

It is entirely possible and correct labeling for a completely naturally produced bottle of vinegar to contain a label indicating that it is 5% acetic acid. Acetic acid is a component of vinegar. Diluted acetic acid does not make vinegar any more than diluted fructose makes fruit juice. Fructose is a *component* of fruit juice, but it is the other trace components in the fruit juice that change it from being mere sugar-water to being fruit juice. The same is true of vinegar vs. diluted acetic acid.

As for the FDA policy on ethyl alcohol...yes, artificial ethyl alcohol is *allowed* for use in food products. That doesn't mean that it is actually used the majority of the time. Yes, I've seen synthetic ethyl alcohol listed in an ingredients list before--on a bottle of cheap wine that a friend brought over to my house. There wasn't a drop of fruit juice in it, and the ingredients were pretty clear about that...as is required by the FDA policy. One really does need to put that quote about synthetic ethyl alcohol to make vinegar in its proper perspective. It was made in the 1960's or earlier...a time when "scientific" was king, and "natural" was viewed with growing suspicion. TANG was considered healthier than orange juice. Women were told that formula feeding their babies was better than breastfeeding, and even given medication to dry up their milk without even asking them if they wanted to dry up their milk. But there have been drastic changes in perception since that time, so I suspect that OPINION statement does not remotely represent reality any more.

As for needing a degree in chemistry to understand food...generally you don't need one. But when you go talking about chemical matters, you should understand them before speaking authoritatively, or trust those who do have the knowledge since none of us can be experts on everything. You mention that ethyl acetate is used in the production of vinegar, and being upset that it is also in nail polish so "obviously" it is not safe for consumption. But ethyl acetate is a synonym for acetic acid! Just because it has usefulness other than as a food product does not make it dangerous. You refer to acetic acid esters as "not natural," but they are naturally occuring in wines (though an over abundance of esters is considered a fault in a wine) and are what give most fruits and flowers their scents. You keep mentioning alcohol in vinegar. There is no alcohol in vinegar if it is produced properly. The alcohol is converted to acetic acid.

Regarding your 7th reference and its question...according to the FDA document that I previously linked to,

Reply
Shanny
01/08/2012 22:53

Ummm, I like that you have done research on vinegar. It is a well known "natural' cleaner in the home for windows etc.... The thing I want to know is why do you put it on your chips? Nobody does that, it is not for sprinkling on your chips, but, it is for using to clean your windows! LOL! You should be using MALT vinegar (brown colour) on your chips. Snicker!

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01/09/2012 00:24

LOL

I don't myself but fish and chip shops all round the country have a bottle of white vinegar... I thought it tasted weird to do it so didn't after the first time.

I use Malt Vinegar for dressings & Apple Cider as well - they're yum & taste TOTALLY different to the white stuff... oddly enough.

LOL

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Zara
01/08/2012 22:57

Hi Eco-Mum. What a great post! I appreciate you sharing your knowledge & research with us. I always thought that those cheap supermarket white vinegar was green, though I had my suspicion. Now I know why my kids get really bad stomach cramps after eating salad with a little drizzle of white vinegar added to it.

In your opinion, which brands would be "safe" to use in food? And which ones are okay for cleaning with? What's the alternative that you use in your household? Btw, I'm also in Australia. Would appreciate some brands that you could get in Australia. Thanks heaps.

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01/09/2012 00:29

Thanks Zara - appreciate it. Am getting slammed over this post right now so its nice to hear some nice-ness :)

I use Apple Cider for dressings, lemon juice for fish & lime juice for salad dressings too (that's yummy with some chilli sauce mixed in).

We buy bulk White Wine Vinegar from our local big food supplier place in 4L bottles & use that for soaking nappies, clothes etc with bicarb soda added in. Its been good for that!

I use watered down White Wine Vinegar for windows with newspaper 1:5 ratio in a spray bottle :)

Does that help? Oh, brands - hang on *runs to cupboard* CORNWELLS!

They're good - I use their brown, apple cider vinegars & they're one of the oldest producers in Oz :)

Does that help? :)

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Zara
01/09/2012 05:00

Thank you so much. Appreciate your input. Btw, do you have an email subscription? I can't find any link to it (maybe I'm not looking in the right place). I saw your article posted on someone's facebook. That's how I got here.

Ps: Keep up the good work... It is definitely an eye opener for me. Don’t let those negative comments get you down. As the saying goes: "All truth passes through three stages. First, it is ridiculed. Second, it is violently opposed. Third, it is accepted as being self-evident".

There are lots of like-minded people that appreciate you presenting & sharing your well researched article.

01/08/2012 23:28

A friend of mine said he's never seen white vinegar that wasn't distilled and that the brand he has in his home is. I looked at ours, and both brands we have are distilled as well. I don't know if it's just our part of the US or the US in general, but I'm relieved! Still, I never would have known to look!

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01/09/2012 00:25

Its SO weird to me that you guys are mentioning WALMART - I'm in Oz, never seen a WALMART but read the book about it (great story!) and hear about it all the time... trips me out to see you guys all the way from the US of A posting on here :)

I didn't think to look either but the Bloodhound in me wanted to know for sure what I was using at home... wish I'd never looked into it now! LOL

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Kimberly
01/09/2012 01:11

I found this post so interesting, thank you!

I use white vinegar in every clothes wash cycle and in the soapy water to disinfect when I'm washing dishes (no dishwasher!).

I am highly allergic to petroleum, having had several allergic reactions that sent me to emergency department in Canada. One allergist I saw suggested that 25% of the population probably has a petroleum allergy.

I've just run to the cupboard to check... distilled white vinegar (barley)!

One reader commented that petroleum jelly (such as Vaseline) is harmless, and a 'zero' in terms of toxicity. This certainly doesn't apply to all people (not me). I'm not convinced the regulations for that 'zero' rating are based on today's standards...

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01/09/2012 01:47

Bless your cotton socks - thankyou :)

You're SO lucky - I can't find anything in terms of "grains" here in Oz except on a few of them... most are very ambiguous in terms of content, production method etc... don't like that at all.

And I totally agree re: your stance on Petroleum Jelly - I stopped using Lucas PawPaw because it has petroleum jelly in it. I don't want that stuff in my home, near my kids - they're SO sensitive, Missy 9mths Old gets a terrible hivey / eczema thing if she munches on a bread crust!

I'm happy for those that have chemical resistance developed however I wonder how long that lasts until they see signs of it not being "resistance" but slow reaction?

Our family, me included, aren't in that category - I react instantly to things like MSG (blushing from my chest up my face, heartburn, headaches - straight away, within minutes!) so we just can't take the risk with things like this.

For all the "chemistry lessons" and related quips I've been copping thus far no one has been able to prove to me the source of white vinegar (distilled or otherwise) as a whole is free from chemicals or synthetic "involvement" in anyway.

Until that day, I ain't touching it! ;-)

And thankyou for your kind words - I appreciate it SO much! xo

P.S. Totally agree with you - the zero rating is based on PUBLICISED information... because big corporates who's income depends on what they do don't EVER hide things from the public now do they??? ;-)

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01/09/2012 02:28

Instead of making, or trying to make, your own environmently safe cleaning products try Nature Direct - perfectly safe AND they work!!

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Bee
01/09/2012 02:49

Thank you for your article... a real eye opener. You have inspired me to start taking a closer look at food labels and questioning where this stuff is coming from.
I think a lot of people are missing the point that you are making and/or trying to up one you! But i get it, and will be following your blog from now on.
Looking forward to reading more busted myths. Keep up the good work!

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01/09/2012 03:24

Hi Bee,

Thankyou so much! I am so glad you liked the post and that you got the point of it ;-)

You are right in that the point of the whole thing is
a) raise awareness
b) evoke reaction in the form of questioning and
c) help work out ways around the issue with known safe alternatives.

Too many times I've been assured that a chemical version of a natural substance is "the same" and it never is - I don't care what the chemical formula for it is! I don't buy into chemical "propaganda" anymore - unless you can prove it to me, unequivocally that its 100% safe, has been tested & found to be for humans, animals, fish, ocean and land then I don't want to touch it...

Anyway, thankyou so much for your support - I appreciate it, from one Eco Mum to another...! :)

xo

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T.E.D.
01/09/2012 03:18

So is a reasonable summary of the issue that in many cases there is no cast iron guarantee that white vinegar (dstilled or otherwise) has been naturally derived as opposed to chemically derived?

Even though some on here say that chemically the substance is the same no matter how it is derived and therefore safe, history has shown in a number of other cases that such assurances are proven in the long term to be ill-founded and it is better to be safe than sorry unless absolutely sure.

In this case, the assurances appear lacking that the white vinegar in question has been naturally derived or created, correct? If so, the post seems to be a reasonable approach to me - employment of the Precautionary Principle in homes is wise and valid no matter how much high school chemistry one has learnt.

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01/09/2012 03:31

Hi T.E.D!

That's a pretty good summation of the posts since the post, yes :)

I agree in that borrowing from the Precautionary Principle, especially in homes where our kids are concerned is vital these days. Without it, there is too much room for exploitation - I've seen in my own life what happens in this instance.

I try to spread awareness - not say I am right - so that people learn to question things now instead of taking it all at face value. Corporates, conglomerates, indeed business in general doesn't do honour the way it used to... you can't trust what you're told anymore.

So, yes, as you say, until the assurances about white vinegar are received from FDA, FSANZ and just about every manufacturer in the world (which isn't possible, really) its not enough for me. I won't be using it again...

... but other Eco Mums can do that they like :) We just present information and options here :)

Thanks for posting & summarising for everyone - it was starting to get a bit confusing :)

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zoemia
01/09/2012 03:47

And you amaze us again you smart cookie you :) It just makes you wonder what else their NOT qriting on the labels hey. Thanks for sharing i sure will be looking at my labels for E260 :)

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01/09/2012 05:59

I completely agree that petroleum has taken over the earth and its extraction and use are destroying our only home and the health of us, our children, all animals and all plants - but - I do wish you hadn't tried to back up the perfectly legitimate, albeit shocking to some, facts with statements such as "The second (although not widely used as its expensive) way of producing acetic acid is through the processing producing “acetaldehyde” (sounds like formaldehyde... does that give you confidence this is healthy stuff?!)". This is the kind of argument-embellishing statement that makes people laugh at the alternative health crowd and causes others to dismiss the point in one fell swoop before they even hear the message properly - as many of the above scornful comments attest. I have no scorn as I know the point you're getting at - that this whole system is messed up and that we who wish for life and health are fed up with always having to be on the defensive for our rights to a nontoxic life - but I want to make a few points about the chemistry (minus the scorn). For starters acetic acid is a naturally forming compound which can be reproduced in a lab by synthetic means; your original post makes it sound like all acetic acid is poisonous and dangerous, when actually it occurs naturally in safe, edible concentrations in brewed vinegar as well as other ferments such as natural, healthy, safe water kefir and kombucha. Secondly, just because one word sounds like another does not mean it means the same thing or even is related. There's a whole group of compounds, which can occur naturally, in chemistry that end with "aldehyde". "Coconut sounds kind of like cocaine, so we'd better avoid eating coconut" is about as pertinent a statement for your cause as the one about acetaldehyde. Please do double check your facts, for your own sake as well as the people who come to your blog looking for the truth (forget about the troublemakers who don't care about your overall cause; they're not worth losing sleep over!) Your can do just fine justifying its outrage about the toxicity of the "food" industry without needing to embellish your agruments. :) Thank you for speaking out on the atrocities of industry!

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EmT
01/10/2012 00:26

Well said. It's the embellishments that destroy the argument.

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fiona
01/09/2012 06:45

Here in the US I just got out my big bottle of store bought white vinegar and see its ingredients listed as " Grain and Water" and its called "White Distilled Vinegar" - this is from a grocery chain here in New England and is a giant gallon bottle. Will keep using this stuff for major (and affordable) green cleaning!

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At the height of my chemical sensitivity there was a vinegar I reacted to and it was a store brand that did not say distilled. I, personally, have never felt ill using one that says 'distilled' on the label.

You got me thinking about Fels-Naptha soap (http://www.felsnaptha.com/) with this "Oh, and Naphtha? That’s a very broad term covering the lightest and most volatile of the liquid hydrocarbons found in... petroleum. "

ewww. Now I've gotta go do some research and see if I can find out what Fels-Naptha is made from!

Thanks for taking the time not only to research this but also to share it with the rest of us :)

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Phoenix
01/09/2012 08:56

I really do appreciate that you're discussing the fact that white vinegar CAN be made synthetically and from petroleum sources. That's been all over green cleaning blogs and message boards for a long time now. It's good to be reminded now and again to check labels and question sources. My problem is your tone, the inflammatory language used and the images used. You may say in the comments section that you're just trying to tell us what you prefer in your own home, but your whole post screams otherwise and I'm sure you're aware of it.

When I first read this post, I was taken aback at the condescending tone which implies that those using vinegar to clean were fools. You even say, "we've all be fooled." Not just you and your home, all of us. Your use of the gravesite and radioactive imagery is inflammatory. Your post still contains the glaringly inaccurate claim that, "Acetic acid = made in a lab or petrochemically derived." Dear God, that is simply not true. As I, and others, have pointed out here, acetic acid can be made in a lab, but it is also very natural as part of the fermentation process.

There is also a problem with the following sentence, "'acetaldehyde process' (sounds like formaldehyde... does that give you confidence this is healthy stuff?!)." Just because two things sound the same does not mean they are the same. In chemistry, an aldehyde is something that produces either an acid or an alcohol, depending on whether or not it was oxidized or reduced. It's not an indication that something is toxic or synthetic. It's part of a chemical reaction. Water is the product of a chemical reaction, so not all chemical reactions are bad.

When you post something like this with this kind of tone and a broad misunderstanding of the chemistry involved, you give us an example of why a lot of us "green living" folk are such a laughing stock. It would have been one thing to say, "Hey, check your white vinegar. It may be derived from petroleum," rather than, "OMGZ!!!! ALL WHITE VINEGAR IS EVIL AND WE'RE ALL SO STUPID IF WE USE IT BECAUSE ALL ACETIC ACID IS FAKE AND BAD BAD BAD STUFF. LOOK! It's radioactive! Look, a grave marker. You'll DIE if you use it!!!!!" Now, that seems silly? Doesn't it? But your post comes off exactly like the latter example. You have good intentions with exposing that some white vinegar isn't benign, but you took it too far and sprinkled it with a lot of chemistry misunderstandings that call into question your whole point. It really seems like I'm attacking you, but I'm not. I keep seeing this article pop up on Facebook and then it results in people either in full on panic or people getting kinda hostile towards you. I don't think either result is what you are looking for. :-)















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01/09/2012 15:21

Hi Phoenix,

Yes, I agree - in some ways, you're right and perhaps moderation of my tone and style would be "appropriate"...

However I don't really do "appropriate" by nature. Its not who I am and if I had done it that way, hardly anyone would have read this.

This is not the first post to be written on the subject but its the first one I've seen with so much controversy around it.

That is not to say I relish the put downs, degrading comments, ridicule and sarcasm but I am strong enough to handle it and keep moving forward.

So, yes, in hindsight a "toned down" version may have been less inflammatory but it would not have created the same outcome - people may ridicule me for this post, that is ok. Other people will start to question their products more now as a result - that to me is a great outcome and one I am happy to have helped created... even if I am copping a flogging for it left, right and centre.

All that aside, I love a good debate and often engage in them myself online however I never stoop to name calling, ridicule, abuse, insults, degrading put downs etc on a personal level, attacking anyone personally. There's no need - when you have a fair, provable point you don't need to engage in that kind of behaviour. When you're a competant communicator, you don't need to engage in that kind of behaviour.

I find that when people start the slanging match they either have a flimsy point that can't stand on its own two feet or they can't communicate clearly enough to get their point across. Either way, that's nothing to do with me.

So whilst I don't reslish the hostility, the fact that it is present at all is more of reflection on the person being hostile than it is on me. I have never been hostile in response - there's no need, its not about me. I feel sorry for the people hurling the abuses and put downs. They can't communicate any other way and that is very unfortunate. I can communicate in other ways and so I do :)

I've done the research and as yet no one can prove to me and everyone else on here that what I am saying is totally wrong. Until that time, the hostility will rage away because people can't communicate their points effectively... and also perhaps because there isn't a point that can be proved conclusively.

From this point, I will watch with amusement sipping on a glass of organic wine as the truth comes out...

Oddly enough, Heinz apparently (though I have not seen it myself) spent a bit of a fortune telling everyone that their vinegar is safe & petro-chemical free. If EVERYONE's vinegar is the same (safe and petro-chemical free), why are they spending money to tell everyone what everyone ELSE is already doing??? No company in their right mind would do that, no Director would approve the expense of it because there's no money in it.

High school chemistry quips aside - the issue smells and my "inflammatory" post has made people sit up and take notice. My work here is done :)

Hindsight is a wonderful thing but I won't shy away from who I am or the fact that this even had to be done in the first place - the "system" is ambiguous and failing us - else why would these posts even need to be written?

Consumers deserve to know for sure, one way or the other... but no one can tell me for sure one way or the other.

Why is that?

Thankyou for your points of view though - I don't feel attacked, in essence and hindsight, you are quite correct. However, what's done is done and I stand by what I've written and hope that more people read it and question the products in their lives as a result! I'll cop the ridicule for that outcome :)

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Phoenix
01/09/2012 16:57

See, that's what I don't get. "What's done is done." I completely agree that we need to get a point out there that these companies aren't on the up and up and that people need to check their labels. But, you can get that point across without the use of the misinformation presented above. You had a chemist on this thread explaining about acetic acid. Others have done the same. I've explained about acetic acid. Why not just edit the post and say, "whoops, I thought all acetic acid was lab created, but some of it does occur naturally." My concern is that you DO have a valid point about SOME vinegar being synthetic and that we need to be vigilant about checking labels. That is a GREAT message. However, there are statements up there that you presented as scientific fact that are simply untrue. That's what people will focus on. They will not focus on the point you want to make about SOME white vinegar being synthetic. They will say, "hey, she doesn't have her facts straight. Maybe we can't trust what she's saying." It does a disservice to your readers to leave false statements up there. Eventually, it won't be taken seriously because the science is misrepresented.

Again, you have quite a valid point about synthetic vinegars and it's getting lost in all of this controversy over acetic acid and the understanding of chemistry. When you say, "what's done is done," it's like you don't care if you spoke the truth or not. Make sense? I suck at writing this out. While you are free to use the language and imagery that you choose, people tend to gloss over that kind of hyperbole and file it under "crazy talk." Like I've said before, the general public (here in America) doesn't view the green movement favorably anymore. It was a trend years ago, but the politics around it has become brutal lately. Us eco folk are seen as crazy conspiracy theorists. Posts like this, while the heart of the message is in the right place, become fodder for people trying to disprove us. I'm afraid that you'll be someone to ridicule more than someone to take seriously.

As for Heinz - the fact that there is white vinegar on the market that is synthetically produced is not unknown. In fact, it's pretty well known. I've read magazine articles, newspaper articles and blogs about it for the past few years. It may be relatively unknown in Australia, but it's definitely not a secret among the green folk in the USA. It comes up in blogs and message boards quite often. Heinz was responding to public perception. I don't think they spend loads of money, because the ads aren't a big deal or in your face as far as advertising goes. They just took the time to say they're natural. Also, dirty secret, Heinz owns and manufactures A LOT of the store brand vinegars. I don't know about Australia, but a lot of generics in the USA are made by brand name companies and sold under different names. Oddly enough, it encourages brand snobbery.

EmT
01/10/2012 00:42

Hear hear!

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01/09/2012 14:38

I am very excited by this article! I swear by my microfibre ENJO and water for cleaning but so many people argue with me that vinegar is better and cheaper. Tests have recently shown how in-effective vinegar is too, which can be viewed at http://www.youtube.com/watch?v=MRwRmjBVQq0 - please do yourself a favour and check it out. I also run a forum of chemical free cleaning hints & tips where everyone shares their secrets to a clean home - please check it out and feel free to share! Together we can make a difference and show these companies we won't stand by and let them destroy our health, the environment and our children's future.

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01/09/2012 14:51

Hi Janelle,

Thankyou SO much for this! I will definitely have a look at your link and forum!

And thankyou for your excitement - it hasn't been easy of late; there's been something like 8000 hits on this article in 48 hours - half of those people appear to be laughing and ridiculing me.

However, I'll take it because something isn't right and it needs to be addressed... NOW!

Thankyou again for your heartfelt support :)

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Mer
01/09/2012 15:03

Now there's something else to investigate....microfiber. Microfiber us made up of polyester and polyamide. Guess where polyester comes from? Petroleum. Polyamide in textiles is synthetic unless it's true silk or wool. Just sayin'

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Phoenix
01/09/2012 17:01

Yep...microfiber is another supposedly "green" tool that's not. There are wool microfiber blends - I *think* - but they are expensive and uncommon. Polyester is a petroleum product. Polyamide is a protein and is either natural or synthetic. As Mer said, a natural form is in silk and wool. The rest is lab created as part of polymerization. I have this argument with people all the time.

Maybe microfiber is another subject to look into?

01/09/2012 14:57

Hi everyone!

I'm sorry but I don't have time to go through and reply individually to every comment now... please don't think I am ignoring or otherwise uniterested in your points of view.

Overall, I am a housewife. I have a daughter. I write for fun & to be kept informed and pass on that information to others.

Regardless of how I've written (alot of which has been misconstrued - p*ss takes and sarcasm taken to be gospel, which its not - people familiar with my writing style know that) the fact remains that I am but a mere housewife.

It is NOT up to me to prove one way or the other that vinegar is or is NOT synthetic. It is up to the FDA, the FSANZ, the manufacturers, suppliers and distributors and the chemists of the world to prove to me and every other house wife in the world who's concerned about this, beyond ALL doubt that it is or is not synthetically produced.

Whilst I enjoy the banter and love a good debate (I do - its good fun, most of the time) I can't devote anymore time to this... I do have a family.

So, I'll put it out there - if anyone can conclusively, 100% prove to me one way or the other, beyond ALL doubt that what I'm saying is totally wrong I'll happily broadcast that truth to all and sundry & state publicly that I am wrong. :)

Otherwise, feel free to keep discussing it - that fact remains, I might be a "failed chemistry student" as some have so delicately put it, but my job is done - you're all reading my "panic stricken, ill-informed ramblings" which means that questions have been and are being asked... this to me is great news and a great outcome!

I'll cop the ridicule and attacks because people are now questioning sources of products. To be, my work here is done :)

Thank you all for your postings - it makes for enjoyable reading! :)

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Liz
01/09/2012 17:47

MMMM well I have done my best to read the posts and to digest the information contained therein. Firslty isn't it great that we are able to discuss these matters openly and without regulations or a threat of being made silent. Secondly, I applaud all of you for taking the time to comment on matters pertaining to what is contained in products we buy and use. Thirdly I congratulate "eco mum" for having the courage to raise these questions, thus fostering such an interesting debate on these important issues. I do believe that some of the "ole" ideas which our grandparents used in the home, in their food, is worth looking at. Think about this, much of what they had was home made, food they ate, was home grown, water they drank was often tank water or boiled creek water. If they were hurt they resorted to using what was in nature to help in the healing process. I think " eco mum" is trying to remind us to be a little more cautious with what we are being told to use, by so called experts. We are quite capable to make an informed decision about how we live, what we eat and what our families eat. Afterall that I believe is what "eco mum" is all about...So thankyou for all the comments, debates and information herein, I feel a little more aware than I was some hours ago, lol lol lol Hang in there "eco mum" xx

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The Eco Mum
01/09/2012 17:48

Hi Phoenix,

Yes, I agree with what you're saying, have considered what I've been told and the post was edited last night to reflect that not ALL acetic acid is synthetically produced...

Apologies for not saying so earlier but I have taken everything everyone has said on board, edited where necessary, provided more sources where requested & still stayed authentic to myself and the message, that being that we can not be 100% sure what we're getting in any white vinegar bottle has been made via natural processes using natural ingredients.

Other than that I don't see there's anything else I can do! The point remains unproven - labelling states that one bottle is acetic acid & another is distilled white spirit & another is fermented grain with distilled spirit.

For me, until the FDA, FSANZ and every vinegar manufacturer in the world say ''Its all made by natural processes & we DO NOT USE any petrochemicals'' the issue remains.

So, when I say what's done is done that is me saying I am not going to run off and hide from my post. I stand by it but have edited accordingly and now am publicly stating that I have done so.

I don't see what else I can do.






























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Phoenix
01/10/2012 13:23

"The point remains unproven - labelling states that one bottle is acetic acid & another is distilled white spirit & another is fermented grain with distilled spirit."

That because, with the way you worded it, they are all the same thing. Those are different ways of saying the same thing.

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Phoenix
01/10/2012 13:32

Ugh. It sent without me finishing. Anyway, it's like saying you have 3 bottles - one says, "water." The other says, "H2O." And the third says, "dihydrogen monoxide." They are all the same thing. Now, the rub would be WHERE that water came from. The tap? A cold mountain spring? A dirty bucket? That would be the issue, but not the different names for the same thing.

Lindsay Gordon
01/09/2012 17:49

My word, some people have small minds and obviously nothing better to do than criticise some one trying to make the world a better place for us all to live in.
Hang in there eco mum and ignore all the so called critics who to my mind still haven't prooved you wrong but in there tiny minds think they are smarter than everyone else.
Its people like you who question the "establishment" and then question their answers who will make the world a better place for the silent majority (me included) who sit back and do very little to protect society from these money grabbing multi nationals whose only god is the mighty dollar.
I doff my hat to you dear lady for having the "guts" to put your findings out ther for everyone read,and to those who poo who your credentials the best university for learning is the university of life.
In conclusion I say to you, "carry on with your crusade and stuff the negative people who criticise you as they will not change the world but you just might make it a better place for us ALL to live in, and I am sure they will take what ever improvements you might make, so BRAVO dear girl and carry on the good work.

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Phoenix
01/10/2012 13:25

That's kind of a harsh thing to to say to people who are trying to help her cause. Personally, I agree with what she is trying to say - read labels and know your sources. People, myself included, are trying to correct her science. She is better armed and will reach even MORE people with less ridicule if she presents the facts correctly. That's all.

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Jessie T
01/09/2012 18:20

When it comes to the health of my children, my husband, our pets and I, better to be safe than sorry. I trust food, not synthetic chemicals. I now use white wine vinegar to clean with, diluting it for my fabric softener at 200ml in a 2L bottle topped up with water and oils. Considering this works out just as cheap as using 1L white vinegar there is, imo, no point running the possible risk, even if it IS minute. If there is a doubt and there is an alternative...

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Suzy
01/09/2012 21:14

One of the points of being environmentally friendly with cleaning products is to use products that cost less to the environment in regards to their production and packaging. And another thing which most mums want to do is to save money (while being environmentally friendly). I think both of these points are relevant for using things like vinegar and bicarb soda for cleaning - we already have them in our homes so are are not paying the environmental cost of having extra factories and manufacturing processes and extra packaging and transport costs. Financially we are better off as we are not paying for fancy packaging of cleaning products (aka water plus a bit of disinfectant or whatever).
A third benefit of using substances like vinegar and bicarb is that we know they are relatively safe compared to some other cleaning products on the market. However due care needs to be taken. Everything on the planet is a "chemical" compound (unless it is an actual element), so I do get annoyed at people who promote products as having "no nasty chemicals" etc in their advertising. And just because something is a petrochemical doesn't necessarily make it evil!

I'm not sure I object to using synthetic acetic acid for my cleaning. I don't know that I will want to pay the extra for "food grade" vinegar for cleaning purposes. However thank you for bringing to our attention that there are different ways of making vinegar. I guess this is why the more expensive vinegars taste better!

I will also take into consideration the rare elements that are used in the production process. You are right, there should be more information available about this and many other things on this planet. Who of us would like to go without our mobile phones and yet there are rare elements used in making those too - perhaps we should all try and hang onto our phones for a bit longer and resist the advertisers telling us we need the latest and greatest phone gizmos as every time we throw out an old phone and get a new one that is another precious resource used up from the limited supply on Earth.

Thanks Louisa for doing research on behalf of everyone who takes an interest in the health of our planet.
~Suzy.

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Phoenix
01/10/2012 13:21

"Acetic acid = made in a lab or petrochemically derived. "

You still have that up there despite saying you edited for facts and it's still not true. Again, acetic acid can be made in a lab. It is also naturally created as part of the fermentation process. I don't understand why you don't want to correct that.

I'm not being mean. Your argument won't be taken seriously because of the holes you left. You have a VALID point. We want to see it taken seriously. That's all.

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01/11/2012 19:25

Hi Phoenix,

Ok, I'll be honest - I am very tired of this post, of comments and I just want to delete the whole thing.

Because that would be cowardice I won't however if you want to send through whatever editing / changes / updates you feel are most appropriate given your vastly superior knowledge to theecomum@gmail.com I will make the changes you request.

I am a full time mum, full time student (studying, funnily enough, chemistry via Bachelor of Naturopathy) and have 2 businesses to run. I don't have time anymore to devote to the back and forth, back and forth on a word for word change.

Please - send me what you most want to see and I'll update accordingly.

This whole process is taking my time away from my family & I won't allow it to continue anymore.

Thankyou for your feedback - feel free to forward your suggestions to me anytime as how you feel this should be written.

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Emma
01/11/2012 01:32

There is so much wrong with your interpretation of this information that I don't even know where to start and couldn't even be bothered responding to every single point, so I'm just going to say one thing:

Just because something is a "chemical" or synthetically derived does not make it inherently "bad" (where would we be without many of the lifesaving medications that are created in a lab?), in the same way that natural things are not always "good" - think about all the poisonous plants that exist. I get that this is not the main point of your post, but it's clear from your writing that this is a belief of yours.

I totally get that you're trying to live an environmentally friendly life and I applaud that, and I'm really disappointed that those companies haven't gotten back to you, but if you had a basic understanding of chemistry you'd realise all the mistakes you've made in your reasoning.

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Deborah Jennings
01/11/2012 07:51

I am trying to get away from "man made" products and getting back to more natural things. Thank you for this post, it does make you think. I do have some white vinegar in my home, but I also have the apple cider vinegar. I really like the apple cider the best. I will be looking for some naturally occurring vinegar to use for my canning and pickling from now on.

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DEB B
01/11/2012 09:05

Thank you for all your time on researching this. It is people like you that make people like me start looking into things and questioning big companies. Your giving your thoughts and what you have found out on your own site. THANK YOU It is up to anyone interested in improving their quality of living to do further research and decide for themselves what they want in their homes. You are just trying to open peoples eyes as to what could be going on. Pretty much the same as most magazines, papers etc. If someone has no issues with living in a chemically, plastic infused home and eating GMO foods etc., I wonder why they are frequenting your site? I personally feel that due too our decline of "natural" living and producing "real" food, it has caused serious issues with our earth, Mother Nature and created numerous health issues, cancers etc. that was not in the past. I do not want my children, grand-children etc. suffer even more. This is my personal opinion and not everyone may agree. Which is fine, but, they should respect others opinions. Keep up the good work of getting people to THINK.

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Heather
01/11/2012 10:31

Hi, guys! I will admit, I have not had the time to read all of the responses to this post, so forgive me if this is redundant...I didn't see any mention of this point:

Apple cider vinegar is often not what it appears to be, either. Yeah, I know, huh?

Watch labels for "apple cider* vinegar"- the fine print will let you in on what that "*" is for. It's "flavored" white vinegar. And has little to no true resemblance to the real stuff.

Thank you, EcoMum, for writing this post- my husband and I ran across the info that you've posted when we were researching azidocarbonimide (a NASTY additive in a lot of bread products over here in the U.S., even supposedly "organic" breads!). Whether the stuff makes people nervous/angry/etc. or not, it's good that the information is getting out there. Folks need to know the facts, ALL of them, in order to make informed choices!

Cheers,
Heather

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JMT
01/11/2012 11:07

Just wondering about the anti-mining stance that really ruins the article for me. Is your computer made of bananas? Does your Internet run by carrier pigeon? Because mining has such a gross impact on you life, you could not possibly sustain the life you live (yes, even an Eco life) without mining. It's a dirty job, but you need us miners

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01/11/2012 11:59

Thanks so much for introducing such an interesting topic. For me the unaccountability or non-disclosure of ingredients is a problem because I need to know what grains are used because of being gluten-free. I also want to know that I am GMO and MONSANTO free. In the end it's not about the chemical composition, for me anyhow; it's about the environmental effects and about whether we should trust blindly in products that are touted as green. Thanks again!

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Thank you for bringing attention to the difference between chemically created vinegar and naturally brewed stuff. I never fully realized the importance behind the differences.

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