So, how many eco websites have you seen touting the supreme green cleaning abilities of WHITE vinegar? (Not to be confused with white WINE vinegar)
For windows, for fabric softening, for tiles, for toilets, for sinks... for just about everything & anything, right? Its great stuff - I've used it... up till now.

… I uncovered a whole lot of half truthes about white vinegar and it appears that it is FAR from being a totally "green" product. In fact, seems to be the whole process of creation to use is pretty UN-green from what I can gather... but like I say, there's a lot of half truths or not quite upfront truths around how its actually made. It was really a challenge to find out anything about it!
White vinegar, in some instances (most cheap stuff I've seen) is also known as food grade "acetic acid". Now, acetic acid is the technical / chemical name for a naturally occuring substance which is vinegar however it is also the synthetic version thereof... so you can have synthetic acetic acid made in a large scale lab / manufacturing plant and you can have the naturally occuring version.
Full strength synthetic acetic acid is actually highly corrosive & the full on rubber gloves need to be worn when handling it in a lab. So its pretty full on stuff to be watering down and eating on our fish.
White vinegar that is food grade acetic acid is generally made in a lab - as far as I can find out.
Its does not appear to be the naturally occuring kind as this is generally referred to on the label i.e. "distilled from grain" etc. The cheaper white vinegars don't appear to be made in a distillery or brewery (like white wine vinegar or apple cider vinegar... basically unless it says "distilled" on the label its not a distilled or fermented product and not the naturally occuring kind - make sense?).
Looks to me like the cheaper white vinegars we use for cleaning our homes are made in a petrie dish (synthetically I mean). Not real keen on that idea am I.
Now, not ALL countries in the world approve the use of synthetically created acetic acid for human consumption - but USA, EU & Australia do. Personally, I am not down with that - at all.
The FDA in USA (whom our own FSA copy from unashamedly) says this about white vinegar production:
“Presently, we authorize the manufacture of vinegar from ethyl alcohol synthesized from natural gas or petroleum derivatives. It is our opinion that most of the distilled spirits used in the production of vinegar are derived from natural gas and petroleum…
FDA POLICY:
Synthetic ethyl alcohol may be used as a food ingredient or in the manufacturing of vinegar or other chemicals for food use, within limitations imposed by the Federal Food, Drug, and Cosmetic Act, the Alcohol Administration Act, and regulations promulgated under these acts”.
Now, if you hunt around a bit, you’ll probably find that white vinegar is touted as being distilled alcohol with grains in it.
Yes, that IS correct - SOME types of white vinegar are naturally derived, distilled from grain... but NOT ALL white vinegars are created equal!
Unless your WHITE vinegar bottle says or makes reference to on the label “distilled” then it likely NOT gone through the distillation & fermentation process and likely been created synthetically using petroleum derivatives and other interesting things.
It appears the differentiating labelling for the synthetic version vs the natural version is “acetic acid”.
Got that? Labelled "Distilled" = likely to be fermented grains with alcohol like rice vinegar for example.
Labelled "Acetic acid" = likely to be made in a lab or petrochemically derived.
Now that may not be in ALL cases but I can't confirm for you either way with ANYONE (I've contacted all major white vinegar companies in Australia numerous times for assurances but none have been forthcoming) AND the information I have found states that most white vinegar production in the States and Australia is through adding alcohol (ethanol) to whatever substance (ethyl acetate is one of them) but doesn't at all involve DISTILLING the vinegar itself. Confusing hey?
Check the label on the bottle if you're unsure or concerned - your white vinegar bottle may say "distilled" or it may say something like “dilute acetic acid 5%”.
From all the resarch I've done and the FDA policy on the matter, it appears when a product is labelled "acetic acid" (which most of the cheapie white vinegars are) that it is probably the synthetically produced version of vinegar created industrially (see the FDA policy above).
In the food industry, acetic acid is recognised by the code E260 & is used in condiments as an acidity regulator. Acetic acid is approved for food in Australia, New Zeland, the EU and USA - not globally.
So not all countries in the world are as silly enough to be legalising this type of thing... oddly enough.

The first and most widely used is Methanol Carbonylation. This involves using carbon monoxide & methanol to produce a reaction to create acetic acid.
In order for that chemical chain reaction to occur, a catalyst is needed. Back in the day, the catalyst was rhodium - a bi-product from platinum mining.
Nowadays, the cheaper & supposedly “greener” alternative is iridium... yet another bi-product from platinum mining & is actually one of the rarest minerals in the earth’s crust.
Its considered an impurity in platinum mining so is extracted & tossed into the acetic acid production processes.
The first company to go with large scale industrial production processes for acetic acid was none other than... MONSANTO. The global genetic engineering giant who produces things like Roundup pesticides and genetically modified seeds.
Don't know about you but when I hear Monstanto involved in ANYTHING I run a mile the other way... that's just me though. You can make up your own mind.
The new process for acetic acid production using iridium is the brain child of BP CHEMICALS.
I'm not really a fan of them either, in terms of natural living & green cleaning!
The second (although not widely used as its expensive) way of producing acetic acid is through a process called “acetaldehyde process”. Again, acetaldehyde CAN be a naturally occuring substance BUT rarely do I see or hear of the natural stuff. Its usually the easily created, petro-chemical version because it uses up left over stuff from the industry.
Yes a good way to use up things but no, not entirely natural, green or eco-friendly. That's my beef here...
Whilst apparently this substance occurs naturally, it appears that the acetaldehyde use in this process is produced via oxidation of butane or light naphtha, or by hydration of ethylene. When butane or light naphtha is heated with air in the presence of various metal ions, including those of manganese, cobalt, and chromium, peroxides form, it then decomposes to produce acetic acid.
Oh, and Naphtha? That’s a very broad term covering the lightest liquid hydrocarbons found in... petroleum.
As I say, its VERY hard to determine from the crappy labelling what type of vinegar you have in your hands - the synthetic version or the "natural" version. Until I know for sure, I won't be using white vinegar at all to clean my home.
Synthetically. Derived. Chemicals. Isn't. Eco. Well, not to me anyway. Again, make up your own mind armed with as many of the facts as I can find.

And another great question - why isn’t this stuff shown CLEARLY on the label? Why do you have to be freakin' Sherlock Holmes to find out that what has been touted as the “Greener Cleaner” is possibly the farthest thing from?
I can’t answer those questions for you or I & I know that FSANZ can’t be BOTHERED answering those questions either. I contacted them several times during research for this too.
But, what I can say is this - you can replace the white vinegar cleaner with lemon juice (KNOWN to be naturally occuring!) for its bleaching properties & softening of fabrics (its the acid that softens fabrics by removing the build up of soap scum from the fibres). You can use apple cider vinegar for around the house cleaning. You can use white WINE vinegar for windows - I just dilute it 1 : 5 and use it in the same way as I did for white vinegar. Works just as well!
There are other vinegars (some white vinegars are also but not many of the el-cheapos from what I've seen) that ARE in fact brewed or fermented and ARE in fact, greener cleaners.
Sorry to be the bearer of more bad news... but its good to know what's what, right?
Love and frustration,
The Eco Mum xo
P.S. I copped a flogging over this article, as you'll see below in the comments. This blog is a green living, green loving, all things natural, NO THINGS chemical blog. Please understand that when I am writing, I am writing from that angle and for that audience - not the wider chemistry circuit, the petrochemical companies or for those who delight in the advances of the petrochemical world. If you are here, reading this try to appreciate that we don't all relish living in a world where we can not escape from pollution - there is just no where to hide from it anymore. Also, please try to understand that as parents, some of us are less than thrilled that we can not protect our children from the onslaught of chemicals affecting the health of their tiny bodies.
I did my very best to find out all I could on this issue & present here. It was not well received by some members of the general public. It was not an easy task and involved months of collecting information, contacting manufacturers, the FDA, FSANZ and a number of other companies - all of whom ignored me.
As requested by some of the readers from the general public, I have however altered the statements which have caused such upset amongst you. I hope that this new edited version is more "palatable" for everyone :)


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